Novel PV recycling method removes EVA at 9 grams per second

A research team in China has developed a novel preheating-assisted mechanical polishing process to separate ethylene-vinyl acetate (EVA) encapsulants from end-of-life photovoltaic modules. The researchers built an adjustable experimental platform to systematically investigate the effects of key processing parameters on EVA removal and recovery.

“The process efficiency, in terms of EVA removal rate and recovery rate, will be systematically evaluated by investigating the effects of three key parameters: preheating temperature, polishing head speed, and tool penetration depth,” the researchers said. “An experimental production line platform has been constructed to enable precise control of these variables.”The researchers used decommissioned monocrystalline silicon modules consisting of front glass, EVA encapsulant, silicon solar cells, rear EVA encapsulant, and a polymer backsheet. After removing the aluminum frames and junction boxes, they heated the backsheets to 250 C and peeled them off with a scraper to expose the rear EVA layer.They then processed the modules using a custom-built, three-axis computer numerical control (CNC) polishing platform equipped with resistance heating and force-feedback systems to maintain a constant load.The experiments covered preheating temperatures ranging from 150 C to 250 C, polishing head speeds of 500 rpm to 4,000 rpm, and tool clearances of 0 mm to 0.5 mm. The researchers calculated EVA removal rates and recovery rates based on mass measurements and processing times.They also used thermal analysis to identify suitable processing temperatures, while microscopy and spectroscopy were employed to assess surface damage, contamination, and the chemical integrity of the recovered EVA. All experiments were performed in triplicate.“Systematic investigation of the key parameters—preheating temperature, rotational speed, and tool penetration depth—established an optimal process window: 200 C, 1000 rpm, and a 0.25 mm tool offset,” the researchers said. “Under these conditions, the process achieved a high delamination efficiency of 9 g/s and an exceptional EVA recovery rate of 99%, while preserving smooth, undamaged silicon wafer surfaces.”The researchers found that the recovered EVA formed cohesive chunks that could be readily collected and subjected to further processing. They said the proposed technique offers potential environmental advantages over conventional thermal and chemical dissolution methods by avoiding toxic emissions and chemical waste.They also noted that the process could improve material recovery by preserving the integrity of both the silicon wafers and the EVA encapsulant.“Crucially, pilot-scale validation has demonstrated that this preheating-assisted mechanical strategy is universally applicable; it is equally effective for both mono-facial and bi-facial modules, as well as for the challenging removal of front-side EVA,” the researchers concluded.The researchers described the technique in “Efficient delamination of back-side EVA from retired photovoltaic modules via preheating-assisted mechanical polishing,” published in Solar Energy Materials and Solar Cells.The research team included scientists from China’s Nanjing University of Aeronautics and Astronautics, Anhui University of Applied Technology, Ycergy (Suzhou) Technology, and Wuxi Institute of Inspection.